Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/161338
Title: Access to planar chiral ferrocenes via N-heterocyclic carbene-catalyzed enantioselective desymmetrization reactions
Authors: Lv, Xiaokang
Xu, Jun
Sun, Cuiyun
Su, Fen
Cai, Yuanlin
Jin, Zhichao
Chi, Robin Yonggui
Keywords: Science::Chemistry
Issue Date: 2022
Source: Lv, X., Xu, J., Sun, C., Su, F., Cai, Y., Jin, Z. & Chi, R. Y. (2022). Access to planar chiral ferrocenes via N-heterocyclic carbene-catalyzed enantioselective desymmetrization reactions. ACS Catalysis, 12(4), 2706-2713. https://dx.doi.org/10.1021/acscatal.2c00001
Project: NRF-NRFI2016-06
NRF-CRP22-2019-0002
RG7/20
RG5/19
MOE2019-T2-2-117
MOE2018-T3-1-003
Journal: ACS Catalysis
Abstract: Ferrocene-derived dicarbaldehydes bearing pro-chiral planes are desymmetrized under the catalysis of chiral N-heterocyclic carbene organic catalysts. The reaction features selective activation and reaction of one of the aldehyde moieties of the ferrocene derivative while leaving the other aldehyde unit untouched. Our reaction affords enantiomerically enriched planar chiral ferrocene products obtained that are amenable for further transformations. Preliminary application studies show encouraging results when our products are explored for catalysis in chemical synthesis and for antimicrobial utilities in pesticide development.
URI: https://hdl.handle.net/10356/161338
ISSN: 2155-5435
DOI: 10.1021/acscatal.2c00001
Schools: School of Physical and Mathematical Sciences 
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acscatal.2c00001.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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