Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/162171
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dc.contributor.authorChen, Jieen_US
dc.contributor.authorVeksha, Andreien_US
dc.contributor.authorFu, Xiaoxuen_US
dc.contributor.authorZhao, Keen_US
dc.contributor.authorHuang, Jijiangen_US
dc.contributor.authorLiang, Lilien_US
dc.contributor.authorLisak, Grzegorzen_US
dc.date.accessioned2022-10-07T05:07:08Z-
dc.date.available2022-10-07T05:07:08Z-
dc.date.issued2022-
dc.identifier.citationChen, J., Veksha, A., Fu, X., Zhao, K., Huang, J., Liang, L. & Lisak, G. (2022). Conversion of reverse osmosis membranes into metal-free carbocatalyst for electrochemical syngas production. Journal of Co2 Utilization, 58, 101908-. https://dx.doi.org/10.1016/j.jcou.2022.101908en_US
dc.identifier.issn2212-9820en_US
dc.identifier.urihttps://hdl.handle.net/10356/162171-
dc.description.abstractReverse osmosis (RO) membranes are widely employed in water treatment, raising needs for developing spent membrane modules waste management system. This study investigates the upcycling of spent RO membranes through a facile two-step process into functional carbocatalysts that can be successfully applied in electrochemical syngas production with tunable CO/H2 ratios. At first, the spent RO membrane module was pyrolyzed at 600 °C into char. The obtained char demonstrated poor electrochemical performance. Therefore, the char was further subjected to a high temperature (700–1000 °C) doping with melamine. The presence of melamine and the heat treatment were found crucial to convert the char into electrochemically active carbocatalysts. The prepared carbocatalysts showed an enhanced electrochemical reduction capability towards CO2 and H2O producing a mixture of CO and H2. The higher heat treatment temperature of the char increased the carbonization degree and the relative content of graphitic N groups. As a result, the carbocatalyst heat-treated at 1000 °C exhibited the highest CO selectivity with Faradaic efficiency up to 70.1%. Moreover, CO/H2 volumetric ratio of syngas could be easily regulated from 3:1 to 1:10 by adjusting applied electrochemical potentials. In this respect, the proposed two-step approach for the carbocatalyst synthesis could be a feasible strategy for addressing the RO membrane waste and producing syngas with suitable composition for a variety of industrial applications.en_US
dc.language.isoenen_US
dc.relation.ispartofJournal of Co2 Utilizationen_US
dc.rights© 2022 Elsevier Ltd. All rights reserved.en_US
dc.subjectEngineering::Civil engineeringen_US
dc.titleConversion of reverse osmosis membranes into metal-free carbocatalyst for electrochemical syngas productionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Civil and Environmental Engineeringen_US
dc.contributor.schoolInterdisciplinary Graduate School (IGS)en_US
dc.contributor.researchNanyang Environment and Water Research Instituteen_US
dc.contributor.researchResidues and Resource Reclamation Centreen_US
dc.identifier.doi10.1016/j.jcou.2022.101908-
dc.identifier.scopus2-s2.0-85123863263-
dc.identifier.volume58en_US
dc.identifier.spage101908en_US
dc.subject.keywordsMetal-Free Catalystsen_US
dc.subject.keywordsPyrolytic Char Nitrogen Dopingen_US
item.grantfulltextnone-
item.fulltextNo Fulltext-
Appears in Collections:CEE Journal Articles
IGS Journal Articles
NEWRI Journal Articles

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