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Title: Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions
Authors: Seah, Jeffery Wee Kiong
Teo, Ronald Hong Xiang
Leung, Pak-Hing
Keywords: Science::Chemistry
Issue Date: 2021
Source: Seah, J. W. K., Teo, R. H. X. & Leung, P. (2021). Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions. Dalton Transactions, 50(46), 16909-16915.
Project: 2019- T1-001-094 
Journal: Dalton Transactions
Abstract: A number of palladacycles containing chiral chelating auxiliaries have been utilized as efficient catalysts for asymmetric hydrophosphination reactions. In all cases, the chiral auxiliaries remained coordinated to the palladium centres throughout the course of the reactions. Despite the presence of a large quantity of powerful tertiary phosphines, which are known to be strong metal ion sequesters, the expected catalyst poisoning was rarely observed in these palladacycle catalyzed processes. This review highlights the unique stereoelectronic features and the important organometallic chemistry of palladacycle catalysts which are essential to their synthetic operations.
ISSN: 1477-9226
DOI: 10.1039/d1dt03134a
Rights: © 2021 The Royal Society of Chemistry. All rights reserved.
Fulltext Permission: none
Fulltext Availability: No Fulltext
Appears in Collections:SPMS Journal Articles

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