Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/162733
Title: An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole
Authors: Zhu, Lizhao
Kinjo, Rei
Keywords: Science::Chemistry
Issue Date: 2022
Source: Zhu, L. & Kinjo, R. (2022). An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole. Angewandte Chemie International Edition, 61(42), e202207631-. https://dx.doi.org/10.1002/anie.202207631
Project: MOE2018-T2-2-048(S)
Journal: Angewandte Chemie International Edition
Abstract: Regioselective Huisgen cycloaddition reaction between 1,2-diboraallene and azide proceeds under catalyst-free and mild conditions to furnish a diboratriazole (2). X-ray diffraction analysis and computational studies confirmed the delocalization of π electrons over the B2 N3 five-membered ring of (2), indicating its aromatic features. Molecule (2) spontaneously releases N2 to form the 2,3-dibora-4-aza-1,3-butenyne derivative (3). The mechanism of a whole reaction profile was extensively investigated by density functional theory (DFT) calculations.
URI: https://hdl.handle.net/10356/162733
ISSN: 1433-7851
DOI: 10.1002/anie.202207631
Rights: © 2022 Wiley-VCHGmbH. All rights reserved. This is the peer reviewed version of the following article: Zhu, L. & Kinjo, R. (2022). An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole. Angewandte Chemie International Edition, 61(42), e202207631-, which has been published in final form at https://doi.org/10.1002/anie.202207631. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
Fulltext Permission: embargo_20231024
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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