Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/163031
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dc.contributor.authorPham, Thang Loien_US
dc.contributor.authorSae-Lao, Patcharapornen_US
dc.contributor.authorToh, Hannah Hui Minen_US
dc.contributor.authorCsókás, Dánielen_US
dc.contributor.authorBates, Roderick Waylanden_US
dc.date.accessioned2022-11-16T07:08:32Z-
dc.date.available2022-11-16T07:08:32Z-
dc.date.issued2022-
dc.identifier.citationPham, T. L., Sae-Lao, P., Toh, H. H. M., Csókás, D. & Bates, R. W. (2022). The total synthesis of raistrickindole A. Journal of Organic Chemistry. https://dx.doi.org/10.1021/acs.joc.2c02033en_US
dc.identifier.issn0022-3263en_US
dc.identifier.urihttps://hdl.handle.net/10356/163031-
dc.description.abstractThe total synthesis of raistrickindole A has been achieved, thereby confirming the proposed structure as an N-hydroxylated DKP. In the first but less selective approach, the DKP was built up by cyclization of a diastereoisomerically mixed N-hydroxylated dipeptide. In the second approach, the same DKP was constructed stereoselectively by the intramolecular Mitsunobu reaction of a hydroxamic acid. The synthesis was completed by a stereoselective oxidative cyclization.en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF-CRP18-2017-01en_US
dc.relation.ispartofJournal of Organic Chemistryen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of Organic Chemistry, copyright © 2022 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.2c02033.en_US
dc.subjectScience::Chemistryen_US
dc.titleThe total synthesis of raistrickindole Aen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemistry, Chemical Engineering and Biotechnologyen_US
dc.identifier.doi10.1021/acs.joc.2c02033-
dc.description.versionSubmitted/Accepted versionen_US
dc.subject.keywordsChemical Synthesisen_US
dc.subject.keywordsOrganic Compoundsen_US
dc.description.acknowledgementWe thank NTU for financial support of this work. This research was partially supported by the National Research Foundation (NRF) Singapore, NRF Competitive Research Programme (CRP), Grant Award Number NRF-CRP18-2017-01.en_US
item.grantfulltextembargo_20231118-
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