Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/163042
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dc.contributor.authorLu, Nanen_US
dc.contributor.authorYan, Xiaoqingen_US
dc.contributor.authorTan, Hui Lingen_US
dc.contributor.authorKobayashi, Hisayoshien_US
dc.contributor.authorYu, Xuehanen_US
dc.contributor.authorLi, Yuezhouen_US
dc.contributor.authorZhang, Jiemeien_US
dc.contributor.authorPeng, Zhengxinen_US
dc.contributor.authorSui, Jingen_US
dc.contributor.authorZhang, Ziyingen_US
dc.contributor.authorLiu, Wenen_US
dc.contributor.authorLi, Renhongen_US
dc.contributor.authorLi, Benxiaen_US
dc.date.accessioned2022-11-17T08:57:27Z-
dc.date.available2022-11-17T08:57:27Z-
dc.date.issued2022-
dc.identifier.citationLu, N., Yan, X., Tan, H. L., Kobayashi, H., Yu, X., Li, Y., Zhang, J., Peng, Z., Sui, J., Zhang, Z., Liu, W., Li, R. & Li, B. (2022). Carbon-catalyzed oxygen-mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen production. International Journal of Hydrogen Energy, 47(65), 27877-27886. https://dx.doi.org/10.1016/j.ijhydene.2022.06.134en_US
dc.identifier.issn0360-3199en_US
dc.identifier.urihttps://hdl.handle.net/10356/163042-
dc.description.abstractWe report an efficient process to dehydrogenate formaldehyde in alkaline solution, catalyzed by carbon nanotubes (CNTs) via a unique reaction mechanism involving molecular O2. The superior catalytic performance of carbon nanotubes (CNTs) compared to the other carbon-based catalysts is attributed to their sp2-carbon-rich surface, hydrophilicity and abundant surface defects, which are the most plausible active sites. Peroxide species originating from the activation of adsorbed molecular oxygen on the CNTs is found to be a key to C–H activation, leading to efficient hydrogen production. The cost-effective carbon-based dehydrogenation catalysts offer new opportunities to the development of novel liquid organic hydrogen carrier technologies.en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relation.ispartofInternational Journal of Hydrogen Energyen_US
dc.rights© 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. This paper was published in International Journal of Hydrogen Energy and is made available with permission of Hydrogen Energy Publications LLC.en_US
dc.subjectEngineering::Chemical engineeringen_US
dc.titleCarbon-catalyzed oxygen-mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen productionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen_US
dc.contributor.organizationCambridge Centre for Advanced Research and Education in Singapore (CARES)en_US
dc.identifier.doi10.1016/j.ijhydene.2022.06.134-
dc.description.versionSubmitted/Accepted versionen_US
dc.identifier.scopus2-s2.0-85133667039-
dc.identifier.issue65en_US
dc.identifier.volume47en_US
dc.identifier.spage27877en_US
dc.identifier.epage27886en_US
dc.subject.keywordsCarbon Catalystsen_US
dc.subject.keywordsDehydrogenationen_US
dc.description.acknowledgementThe authors are grateful for financial supports from the National Natural Science Foundation of China (No. 21872123 and 22172143). H.L.Tan and W.Liu acknowledge funding from National Research Foundation of Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme.en_US
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item.grantfulltextembargo_20240807-
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