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DC Field | Value | Language |
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dc.contributor.author | Lu, Nan | en_US |
dc.contributor.author | Yan, Xiaoqing | en_US |
dc.contributor.author | Tan, Hui Ling | en_US |
dc.contributor.author | Kobayashi, Hisayoshi | en_US |
dc.contributor.author | Yu, Xuehan | en_US |
dc.contributor.author | Li, Yuezhou | en_US |
dc.contributor.author | Zhang, Jiemei | en_US |
dc.contributor.author | Peng, Zhengxin | en_US |
dc.contributor.author | Sui, Jing | en_US |
dc.contributor.author | Zhang, Ziying | en_US |
dc.contributor.author | Liu, Wen | en_US |
dc.contributor.author | Li, Renhong | en_US |
dc.contributor.author | Li, Benxia | en_US |
dc.date.accessioned | 2022-11-17T08:57:27Z | - |
dc.date.available | 2022-11-17T08:57:27Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | Lu, N., Yan, X., Tan, H. L., Kobayashi, H., Yu, X., Li, Y., Zhang, J., Peng, Z., Sui, J., Zhang, Z., Liu, W., Li, R. & Li, B. (2022). Carbon-catalyzed oxygen-mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen production. International Journal of Hydrogen Energy, 47(65), 27877-27886. https://dx.doi.org/10.1016/j.ijhydene.2022.06.134 | en_US |
dc.identifier.issn | 0360-3199 | en_US |
dc.identifier.uri | https://hdl.handle.net/10356/163042 | - |
dc.description.abstract | We report an efficient process to dehydrogenate formaldehyde in alkaline solution, catalyzed by carbon nanotubes (CNTs) via a unique reaction mechanism involving molecular O2. The superior catalytic performance of carbon nanotubes (CNTs) compared to the other carbon-based catalysts is attributed to their sp2-carbon-rich surface, hydrophilicity and abundant surface defects, which are the most plausible active sites. Peroxide species originating from the activation of adsorbed molecular oxygen on the CNTs is found to be a key to C–H activation, leading to efficient hydrogen production. The cost-effective carbon-based dehydrogenation catalysts offer new opportunities to the development of novel liquid organic hydrogen carrier technologies. | en_US |
dc.description.sponsorship | National Research Foundation (NRF) | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | International Journal of Hydrogen Energy | en_US |
dc.rights | © 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved. This paper was published in International Journal of Hydrogen Energy and is made available with permission of Hydrogen Energy Publications LLC. | en_US |
dc.subject | Engineering::Chemical engineering | en_US |
dc.title | Carbon-catalyzed oxygen-mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen production | en_US |
dc.type | Journal Article | en |
dc.contributor.school | School of Chemical and Biomedical Engineering | en_US |
dc.contributor.organization | Cambridge Centre for Advanced Research and Education in Singapore (CARES) | en_US |
dc.identifier.doi | 10.1016/j.ijhydene.2022.06.134 | - |
dc.description.version | Submitted/Accepted version | en_US |
dc.identifier.scopus | 2-s2.0-85133667039 | - |
dc.identifier.issue | 65 | en_US |
dc.identifier.volume | 47 | en_US |
dc.identifier.spage | 27877 | en_US |
dc.identifier.epage | 27886 | en_US |
dc.subject.keywords | Carbon Catalysts | en_US |
dc.subject.keywords | Dehydrogenation | en_US |
dc.description.acknowledgement | The authors are grateful for financial supports from the National Natural Science Foundation of China (No. 21872123 and 22172143). H.L.Tan and W.Liu acknowledge funding from National Research Foundation of Singapore under its Campus for Research Excellence and Technological Enterprise (CREATE) programme. | en_US |
item.fulltext | With Fulltext | - |
item.grantfulltext | embargo_20240807 | - |
Appears in Collections: | SCBE Journal Articles |
Files in This Item:
File | Description | Size | Format | |
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Carbon catalyzed oxygen mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen production.pdf Until 2024-08-07 | Full Text | 2.36 MB | Adobe PDF | Under embargo until Aug 07, 2024 |
Carbon catalyzed oxygen mediated dehydrogenation of formaldehyde in alkaline solution for efficient hydrogen production SI.pdf Until 2024-08-07 | Supporting Information | 977.25 kB | Adobe PDF | Under embargo until Aug 07, 2024 |
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