Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/163144
Title: Construction of Co-Mn Prussian blue analog hollow spheres for efficient aqueous Zn-ion batteries
Authors: Zeng, Yinxiang
Lu, Xue Feng
Zhang, Song Lin
Luan, Deyan
Li, Sheng
Lou, Xiong Wen David
Keywords: Engineering::Chemical engineering
Issue Date: 2021
Source: Zeng, Y., Lu, X. F., Zhang, S. L., Luan, D., Li, S. & Lou, X. W. D. (2021). Construction of Co-Mn Prussian blue analog hollow spheres for efficient aqueous Zn-ion batteries. Angewandte Chemie International Edition, 60(41), 22189-22194. https://dx.doi.org/10.1002/anie.202107697
Project: MOE2017-T2-2-003 
MOE2019-T2-2-049 
Journal: Angewandte Chemie International Edition 
Abstract: Prussian blue analogs (PBAs) are considered as reliable and promising cathode materials for aqueous Zn-ion batteries (AZIBs), but they suffer from low capacity and poor cycling stability due to insufficient active sites and structural damage caused by the ion insertion/extraction processes. Herein, a template-engaged ion exchange approach has been developed for the synthesis of Co-substituted Mn-rich PBA hollow spheres (CoMn-PBA HSs) as cathode materials for AZIBs. Benefiting from the multiple advantageous features including hollow structure, abundant active sites, fast Zn2+ ion diffusion, and partial Co substitution, the CoMn-PBA HSs electrode shows efficient zinc ion storage properties in terms of high capacity, decent rate capability and prolonged cycle life.
URI: https://hdl.handle.net/10356/163144
ISSN: 1433-7851
DOI: 10.1002/anie.202107697
Schools: School of Chemical and Biomedical Engineering 
Rights: © 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SCBE Journal Articles

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