Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/163251
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dc.contributor.authorLi, Zi-Jianen_US
dc.contributor.authorLei, Minen_US
dc.contributor.authorBao, Hongliangen_US
dc.contributor.authorJu, Yuen_US
dc.contributor.authorLu, Huangjieen_US
dc.contributor.authorLi, Yongxinen_US
dc.contributor.authorZhang, Zhi-Huien_US
dc.contributor.authorGuo, Xiaofengen_US
dc.contributor.authorQian, Yuanen_US
dc.contributor.authorHe, Ming-Yangen_US
dc.contributor.authorWang, Jian-Qiangen_US
dc.contributor.authorLiu, Weien_US
dc.contributor.authorLin, Jianen_US
dc.date.accessioned2022-11-29T06:57:30Z-
dc.date.available2022-11-29T06:57:30Z-
dc.date.issued2021-
dc.identifier.citationLi, Z., Lei, M., Bao, H., Ju, Y., Lu, H., Li, Y., Zhang, Z., Guo, X., Qian, Y., He, M., Wang, J., Liu, W. & Lin, J. (2021). A cationic thorium-organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognition. Chemical Science, 12(48), 15833-15842. https://dx.doi.org/10.1039/d1sc03709aen_US
dc.identifier.issn2041-6520en_US
dc.identifier.urihttps://hdl.handle.net/10356/163251-
dc.description.abstractSingle-crystal-to-single-crystal transformation of metal-organic frameworks has been met with great interest, as it allows for the creation of new materials in a stepwise manner and direct visualization of structural transitions when subjected to external stimuli. However, it remains a peculiarity among numerous metal-organic frameworks, particularly for the ones constructed from tetravalent metal cations. Herein, we present a cationic thorium-organic framework displaying unprecedented triple single-crystal-to-single-crystal transformations in organic solvents, water, and NaIO3 solution. Notably, both the interpenetration conversion and topological change driven by the SC-SC transformation have remained elusive for thorium-organic frameworks. Moreover, the single-crystal-to-single-crystal transition in NaIO3 solution can efficiently and selectively turn the ligand-based emission off, leading to the lowest limit of detection (0.107 μg kg-1) of iodate, one of the primary species of long-lived fission product 129I in aqueous medium, among all luminescent sensors.en_US
dc.language.isoenen_US
dc.relation.ispartofChemical Scienceen_US
dc.rights© 2021 The Author(s). Published by the Royal Society of Chemistry. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.en_US
dc.subjectScience::Chemistryen_US
dc.titleA cationic thorium-organic framework with triple single-crystal-to-single-crystal transformation peculiarities for ultrasensitive anion recognitionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1039/d1sc03709a-
dc.description.versionPublished versionen_US
dc.identifier.pmid35024107-
dc.identifier.scopus2-s2.0-85121720815-
dc.identifier.issue48en_US
dc.identifier.volume12en_US
dc.identifier.spage15833en_US
dc.identifier.epage15842en_US
dc.subject.keywordsAnion Recognitionen_US
dc.subject.keywordsCationicsen_US
dc.description.acknowledgementThis work was supported by the National Natural Science Foundation of China (22076196, 21906163, and 21876182), the Young Taishan Scholars Program (tsqn201909082), Natural Science Foundation of Shandong Province (ZR201910290031), the Strategic Priority Research Program of the Chinese Academy of Sciences (XDA21000000), and the K. C.Wong Education Foundation (GJTD-2018-10).en_US
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