Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/163798
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dc.contributor.authorZhu, Jingen_US
dc.contributor.authorChen, Xiaoyuen_US
dc.contributor.authorThang, Ai Qinen_US
dc.contributor.authorLi, Fei-Longen_US
dc.contributor.authorChen, Dongen_US
dc.contributor.authorGeng, Hongboen_US
dc.contributor.authorRui, Xianhongen_US
dc.contributor.authorYan, Qingyuen_US
dc.date.accessioned2022-12-19T04:44:12Z-
dc.date.available2022-12-19T04:44:12Z-
dc.date.issued2022-
dc.identifier.citationZhu, J., Chen, X., Thang, A. Q., Li, F., Chen, D., Geng, H., Rui, X. & Yan, Q. (2022). Vanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storage. SmartMat, 3(3), 384-416. https://dx.doi.org/10.1002/smm2.1091en_US
dc.identifier.issn2688-819Xen_US
dc.identifier.urihttps://hdl.handle.net/10356/163798-
dc.description.abstractWith the excessive consumption of non-renewable resources, the exploration of effective and durable materials is highly sought after in the field of sustainable energy conversion and storage system. In this aspect, metal-organic frameworks (MOFs) are a new class of crystalline porous organic-inorganic hybrid materials. MOFs have recently been gaining traction in energy-related fields. Owing to the coordination flexibility and multiple accessible oxidation states of vanadium ions or clusters, Vanadium-MOFs (VMOFs) possess unique structural characteristics and satisfactory electrochemical properties. Furthermore, V-MOFs derived materials also exhibit superior electrical conductivity and stability when used as electrocatalysts and electrode materials. This review summarizes the research progress of V-MOFs (inclusive of pristine V-MOFs, V/M-MOFs and POV-based MOFs) and their derivatives (vanadium oxides, carboncoated vanadium oxide, vanadium phosphate, vanadate, and other vanadium doped nanomaterials) in electrochemical energy conversion (water splitting, oxygen reduction reaction) and energy storage (supercapacitor, rechargeable battery). Future possibilities and challenges for V-MOFs and their derivatives in terms of design and synthesis are discussed. Lastly, their applications in energy-related fields are also highlighted.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF2016NRF‐NRFI001‐22en_US
dc.relation2020‐T1‐001‐031en_US
dc.relation.ispartofSmartMaten_US
dc.rights© 2022 The Authors. SmartMat published by Tianjin University and John Wiley & Sons Australia, Ltd. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly citeden_US
dc.subjectEngineering::Materials::Energy materialsen_US
dc.subjectEngineering::Materials::Functional materialsen_US
dc.titleVanadium-based metal-organic frameworks and their derivatives for electrochemical energy conversion and storageen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science and Engineeringen_US
dc.identifier.doi10.1002/smm2.1091-
dc.description.versionPublished versionen_US
dc.identifier.issue3en_US
dc.identifier.volume3en_US
dc.identifier.spage384en_US
dc.identifier.epage416en_US
dc.subject.keywordsDerivativesen_US
dc.subject.keywordsElectrocatalysisen_US
dc.description.acknowledgementThe authors gratefully acknowledge the National Natural Science Foundation of China (Nos. 51972067, 22001021, 51802044, 51902062 and 51802043), Guangdong Natural Science Funds for Distinguished Young Scholar (No.2019B151502039), Natural Science Foundation of Jiangsu Province (No. BK20201048), Natural Science Research Project of Higher Education Institutions in Jiangsu Province (No. 20KJB150008), Singapore MOE AcRF Tier 1(No. 2020‐T1‐001‐031), the Open Fund of State Key Laboratory of Tea Plant Biology and Utilization (No.SKLTOF20190119), and the National Research Foundation of Singapore (NRF) Investigatorship (No. NRF2016NRF‐NRFI001‐22).en_US
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