Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/168971
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dc.contributor.authorTang, Siqien_US
dc.contributor.authorLiang, Jiamingen_US
dc.contributor.authorLi, Ouyangen_US
dc.contributor.authorShao, Ningningen_US
dc.contributor.authorJin, Yongshengen_US
dc.contributor.authorNi, Jinrenen_US
dc.contributor.authorFei, Xunchangen_US
dc.contributor.authorLi, Zhenshanen_US
dc.date.accessioned2023-06-26T01:20:33Z-
dc.date.available2023-06-26T01:20:33Z-
dc.date.issued2023-
dc.identifier.citationTang, S., Liang, J., Li, O., Shao, N., Jin, Y., Ni, J., Fei, X. & Li, Z. (2023). Morphology-tailored hydroxyapatite nanocarrier for rhizosphere-targeted phosphorus delivery. Small, 19(14), 2206954-. https://dx.doi.org/10.1002/smll.202206954en_US
dc.identifier.issn1613-6810en_US
dc.identifier.urihttps://hdl.handle.net/10356/168971-
dc.description.abstractHigh hydrophilicity and soil fixation collectively hamper the delivery of phosphorus (P) released from conventional chemical phosphorus fertilizers (CPFs) to plant rhizosphere for efficient uptake. Here, a phosphorus nutrient nanocarrier (PNC) based on morphology-tailored nanohydroxyapatite (HAP) is constructed. By virtue of kinetic control of building blocks with designed calcium phosphate intermediates, rod-like and hexagonal prism-like PNCs are synthesized, both having satisfactory hydrophobicity (water contact angle of 105.4–132.9°) and zeta potential (−17.43 to −58.4 mV at pH range from 3 to 13). Greenhouse experiments demonstrate that the P contents increase by up to 183% in maize rhizosphere and up to 16% in maize biomass when compared to the CPF. Due to the water potential gradient driven by photosynthesis and transpiration, both PNCs are stably transported to maize rhizosphere, and they are capable to counteract soil fixation prior to uptake by plant roots. Within the synergies of the HAP morphological characteristics and triggered phosphate starvation response, root anatomy confirms that two pathways are elucidated to enhance plant P replenishment from the PNCs. Together with structure tunability and facile synthesis, our results offer a new nanodelivery prototype to accommodate plant physiological traits by tailoring the morphology of HAP.en_US
dc.language.isoenen_US
dc.relation.ispartofSmallen_US
dc.rights© 2023 Wiley-VCH GmbH. All rights reserved.en_US
dc.subjectEngineering::Environmental engineeringen_US
dc.titleMorphology-tailored hydroxyapatite nanocarrier for rhizosphere-targeted phosphorus deliveryen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Civil and Environmental Engineeringen_US
dc.identifier.doi10.1002/smll.202206954-
dc.identifier.pmid19-
dc.identifier.scopus2-s2.0-85145720714-
dc.identifier.issue14en_US
dc.identifier.volume19en_US
dc.identifier.spage2206954en_US
dc.subject.keywordsPhosphate Starvation Responseen_US
dc.subject.keywordsPhosphorus Nutrient Nanocarriersen_US
dc.description.acknowledgementThe authors acknowledge the financial support from the National Natural Science Foundation of China (41171005 and 32202605) and the National Key Research and Development Program of China (2022YFC3201801).en_US
item.grantfulltextnone-
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