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https://hdl.handle.net/10356/170104| Title: | N-phosphinoamidinato silicon(I) and silicon(II) compounds | Authors: | Phang, Isabel Si Jia | Keywords: | Science::Chemistry | Issue Date: | 2023 | Publisher: | Nanyang Technological University | Source: | Phang, I. S. J. (2023). N-phosphinoamidinato silicon(I) and silicon(II) compounds. Master's thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/170104 | Abstract: | This thesis describes the synthesis of N-phosphinoamidinate-stabilized disilicon(I) [LSi-SiL] (L = tBu2PNC(Ph)NAr, Ar = 2,6-iPr2C6H3) 4 by the reduction of its trichlorosilane [LSiCl3, 2] and chlorosilicon(II) [LSiCl, 6] counterpart with KC8. Compounds 4 and 6 were then able to rapidly reduce CO2 to CO at room temperature in toluene to form 7 and 8 respectively. In addition, the chlorosilicon(II) 6 was also able to react with BI3 in toluene to afford a heterodinuclear silicon-boron complex 9. | URI: | https://hdl.handle.net/10356/170104 | DOI: | 10.32657/10356/170104 | Schools: | School of Chemistry, Chemical Engineering and Biotechnology | Rights: | This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0). | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | CCEB Theses |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Final Thesis (Isabel).pdf | 4.54 MB | Adobe PDF |  View/Open |
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