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https://hdl.handle.net/10356/171088| Title: | Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes | Authors: | Feng, Zhongtao Wang, Liliang Sharifah Nadhirah Binte Shaik Mohammed Rao, Bin Kinjo, Rei |
Keywords: | Science::Chemistry | Issue Date: | 2023 | Source: | Feng, Z., Wang, L., Sharifah Nadhirah Binte Shaik Mohammed, Rao, B. & Kinjo, R. (2023). Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes. Chemistry - An Asian Journal, 18(19), e202300634-. https://dx.doi.org/10.1002/asia.202300634 | Project: | MOE−T2EP10220-0002 | Journal: | Chemistry - An Asian Journal | Abstract: | The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2 ) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au-Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic carbene) to afford germanium gold(I) complexes (5 and 6). Chlorine abstraction of 6 gives the cationic germylene gold(I) complex 7. | URI: | https://hdl.handle.net/10356/171088 | ISSN: | 1861-4728 | DOI: | 10.1002/asia.202300634 | Schools: | School of Chemistry, Chemical Engineering and Biotechnology | Rights: | © 2023 Wiley-VCHGmbH. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1002/asia.202300634. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | CCEB Journal Articles |
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| Reactivity of Cyclic (Alkyl)(amino)germylene towards Copper(I) and Gold(I) Complexes.pdf | 550.21 kB | Adobe PDF |  View/Open |
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