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Title: Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
Authors: Lim, Maricar Bungabong
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2008
Source: Lim, M. B. (2008). Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide.
DOI: 10.32657/10356/20676
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

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