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Title: Copper-catalysed β-silylation of α,β-unsaturated esters under mild reaction conditions.
Authors: Siti Suhaila Sulaiman.
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2010
Abstract: A highly-efficient β-silylation of α, β-unsaturated esters was developed, utilizing N-heterocyclic carbene copper(I) catalyst via a unique protocol based on Si ̶B activation. By employing MeOH as a basic additive which is necessary to promote the reaction, the β-silylation products can be readily obtained. All the reactions proceeded at room temperature with good yields. A mechanistic cycle has been proposed to account for the process.
Fulltext Permission: restricted
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Student Reports (FYP/IA/PA/PI)

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