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Title: | Synthesis of substituted pyrrolo- and indolo-quinoxalines via the gold(i)-catalyzed tandem hydroamination-hydroarylation of pyrrole- and indole-substituted anilines with aromatic terminal alkynes. | Authors: | Koh, Chii Boon. | Keywords: | DRNTU::Science::Chemistry::Organic chemistry | Issue Date: | 2010 | Abstract: | A concise, asymmetric synthesis of substituted 3-pyrrolines from the corresponding amino-homoallylic alcohols derived from amino acids is described. The key step is an intramolecular hydroamination reaction catalyzed by copper(II) triflate. The 3-pyrroline products were obtained in moderate to good yields and with excellent diastereoselectivity and enantioselectivity. | URI: | http://hdl.handle.net/10356/40106 | Schools: | School of Physical and Mathematical Sciences | Fulltext Permission: | restricted | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Student Reports (FYP/IA/PA/PI) |
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fyp report final-edited.pdf Restricted Access | 1.52 MB | Adobe PDF | View/Open |
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