dc.contributor.authorLuo, Ding
dc.date.accessioned2010-07-26T02:47:36Z
dc.date.accessioned2017-07-23T08:43:15Z
dc.date.available2010-07-26T02:47:36Z
dc.date.available2017-07-23T08:43:15Z
dc.date.copyright2010en_US
dc.date.issued2010
dc.identifier.citationLuo, D. (2010). Syntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactions. Doctoral thesis, Nanyang Technological University, Singapore.
dc.identifier.urihttp://hdl.handle.net/10356/41625
dc.description.abstractThis thesis describes the asymmetric syntheses of bifunctionalized phosphine complexes, which contain a stereogenic center at phosphorus, through various reactions, including insertion, hydrophosphination, hydration, and hydroamination. Promoted by the coordination of diprop-1-ynylphenylphosphine to ruthenium, the two alkyne moieties thereafter were functionalized by different reactions, which thus led to the formation of a chiral phosphorous center. This strategy presented is valuable and can be widely used in the synthesis of chiral phosphines.en_US
dc.format.extent297 p.en_US
dc.language.isoenen_US
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compoundsen_US
dc.titleSyntheses of bifunctionalized phosphine complexes via ruthenium promoted stepwise hydrophosphination, insertion, hydration, and hydroamination reactionsen_US
dc.typeThesis
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.supervisorLeung Pak Hing (SPMS)en_US
dc.description.degreeDOCTOR OF PHILOSOPHY (SPMS)en_US


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