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Title: Asymmetric synthesis of phosphines via chiral cyclopalladium(II) complexes promoted reactions
Authors: Yi, Zhang
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Issue Date: 2009
Source: Yi, Z. (2009). Asymmetric synthesis of phosphines via chiral cyclopalladium(II) complexes promoted reactions. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: In this thesis, a systematic review of chiral phosphines and hydrophosphination reactions are described in Chapter 1. This chapter reviews the significance of chiral phosphines and their classification: chiral phosphines with Pchiral center(s), with chiral center(s) in the side-chain or axial chirality in the sidechain and chiral phosphines based on ferrocene. Their synthetic strategies are also discussed. In addition, acid catalyzed-, base catalyzed-, free radical mediated-, transition metal catalyzed-, transition metal complex promoted- and organocatalytic-hydrophosphination reactions are demonstrated.
Description: 260 p.
DOI: 10.32657/10356/47508
Rights: Nanyang Technological University
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

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