Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/48065
Title: Part I Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents Part II NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
Authors: Yin, Peng
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Issue Date: 2011
Source: Yin, P. (2011). Part I Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents Part II NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks in organic synthesis, and are also used as starting materials for the synthesis of many compounds such as amino acids, and different alkaloids. Two catalytic systems for the allylic amination with aqueous ammonia and ammonia gas were well-developed.
URI: https://hdl.handle.net/10356/48065
DOI: 10.32657/10356/48065
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

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