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|Title:||Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines||Authors:||Huang, Yinhua||Keywords:||DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds||Issue Date:||2012||Source:||Huang, Y. H. (2012). Asymmetric C-P bond formation via hydrophosphination activated by palladacycles : synthesis of chiral tertiary phosphines. Doctoral thesis, Nanyang Technological University, Singapore.||Abstract:||This thesis, consisting of three chapters, describes the development of asymmetric C-P bond formation (including C*-P, C*-P*, and double C*-P) via hydrophosphination reactions activated by palladacycles. This methodology provides the access to a series of tertiary C-stereogenic monophosphines, C- and P-stereogenic monophosphines, and C-stereogenic PCP diphosphines (chiral PCP pincer ligands) in high yields with excellent stereoselectivities.||URI:||https://hdl.handle.net/10356/48148||DOI:||10.32657/10356/48148||Fulltext Permission:||open||Fulltext Availability:||With Fulltext|
|Appears in Collections:||SPMS Theses|
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