Application of palladacycle complexes in C-C, C-N and C-P bonds formation reactions
Date of Issue2012
School of Physical and Mathematical Sciences
This thesis describes the application of chiral NC-palladacycle in synthesis of chiral PN containing ligands via promoted formation of C-N and C-P bonds by asymmetric hydroamination and hydrophosphination reaction, respectively. An extended application in selective formation of C-N and C-C bonds via palladacycle-catalyzed allylic amination/ arylation of allylic alcohol is also explored in this thesis.