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https://hdl.handle.net/10356/48428
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Lin, Yuhan | |
dc.date.accessioned | 2012-04-23T07:01:54Z | |
dc.date.available | 2012-04-23T07:01:54Z | |
dc.date.copyright | 2011 | en_US |
dc.date.issued | 2011 | |
dc.identifier.uri | http://hdl.handle.net/10356/48428 | |
dc.description.abstract | Bis[(3,4-dimethylphosphole) Pentacarbonyltungsten] sulfide, 3 , the precursor of P-S-P linked phosphinidene, 2, undergoes a [2+2] cycloaddition, followed by a Cope rearrangement to form the [4+4] cycloaddition adduct, 5. The mechanism has been proven by the isolation and characterization of the [2+2] cycloaddition adduct, 4. From optimization of compound 5, it was found to work best with visible light irradiation using dichloromethane as the solvent. | en_US |
dc.format.extent | 72 p. | en_US |
dc.language.iso | en | en_US |
dc.subject | DRNTU::Science | en_US |
dc.title | Expanding the chemistry of thiolyl derivatives of phospholes | en_US |
dc.type | Thesis | |
dc.contributor.school | School of Physical and Mathematical Sciences | en_US |
dc.description.degree | Master of Science | en_US |
dc.contributor.supervisor2 | Francois Mathey | en_US |
item.fulltext | With Fulltext | - |
item.grantfulltext | restricted | - |
Appears in Collections: | SPMS Theses |
Files in This Item:
File | Description | Size | Format | |
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SPMSG1000498G.pdf Restricted Access | 1.07 MB | Adobe PDF | View/Open |
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