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dc.contributor.authorYue, Yannien
dc.identifier.citationYue, Y. (2012). Rhodium-catalyzed coupling reactions with acyl- and vinylsilanes. Doctoral thesis, Nanyang Technological University, Singapore.en
dc.description.abstractOrganosilicon compounds have attracted synthetic organic chemists because they have a potential to be used as the organometallic reagents which are stable in the air and water. As the recent transition metal-catalyzed reactions developed, catalytic reactions with organosilicon compounds have been also studied. However, most of the reported transition metal-catalyzed reactions with organosilicon compounds require the addition of at least a stoichiometric amount of fluoride salt and/or the introduction of heteroatom such as halogen or alkoxy group on the silicon atom. These activation methods are not economical because fluoride sources are expensive. Introduction of a heteroatom on the silicon atom makes the reagents unstable against hydrolysis and self-condensation. Thus synthetic organic chemists have studied on the methods to activate C–Si bonds of tetraorganosilicon compounds without adding any additional reagents. In this thesis, the author describes a novel synthetic reaction of tetraorganosilicon compounds, triorgano(vinyl)- and triorgano(acyl)silanes, catalyzed by a rhodium complex.en
dc.format.extent152 p.en
dc.titleRhodium-catalyzed coupling reactions with acyl- and vinylsilanesen
dc.contributor.supervisorMotoki Yamaneen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.description.degreeDOCTOR OF PHILOSOPHY (SPMS)en
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