dc.contributor.authorYue, Yanni
dc.date.accessioned2012-05-21T04:50:17Z
dc.date.accessioned2017-07-23T08:43:39Z
dc.date.available2012-05-21T04:50:17Z
dc.date.available2017-07-23T08:43:39Z
dc.date.copyright2012en_US
dc.date.issued2012
dc.identifier.citationYue, Y. (2012). Rhodium-catalyzed coupling reactions with acyl- and vinylsilanes. Doctoral thesis, Nanyang Technological University, Singapore.
dc.identifier.urihttp://hdl.handle.net/10356/49508
dc.description.abstractOrganosilicon compounds have attracted synthetic organic chemists because they have a potential to be used as the organometallic reagents which are stable in the air and water. As the recent transition metal-catalyzed reactions developed, catalytic reactions with organosilicon compounds have been also studied. However, most of the reported transition metal-catalyzed reactions with organosilicon compounds require the addition of at least a stoichiometric amount of fluoride salt and/or the introduction of heteroatom such as halogen or alkoxy group on the silicon atom. These activation methods are not economical because fluoride sources are expensive. Introduction of a heteroatom on the silicon atom makes the reagents unstable against hydrolysis and self-condensation. Thus synthetic organic chemists have studied on the methods to activate C–Si bonds of tetraorganosilicon compounds without adding any additional reagents. In this thesis, the author describes a novel synthetic reaction of tetraorganosilicon compounds, triorgano(vinyl)- and triorgano(acyl)silanes, catalyzed by a rhodium complex.en_US
dc.format.extent152 p.en_US
dc.language.isoenen_US
dc.subjectDRNTU::Science::Chemistryen_US
dc.titleRhodium-catalyzed coupling reactions with acyl- and vinylsilanesen_US
dc.typeThesis
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.supervisorMotoki Yamane (SPMS)en_US
dc.description.degreeDOCTOR OF PHILOSOPHY (SPMS)en_US


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