Synthesis of metal (Iminophosphinoyl)(thiophosphinoyl) methanide and methanediide complexes.
Date of Issue2012
School of Physical and Mathematical Sciences
This thesis describes the synthesis and characterization of metal bis(phosphinoyl)methanide and methanediide complexes. Chapter 1 describes the synthesis of bis(phosphinoyl)methane with two different coordination site. Chapter 2 describes the synthesis of main-group metals iminophosphinoyl)(thiophosphinoyl)methanediide complex derived from magnesium, aluminium and tin(II). Chapter 3 describes the synthesis of transition metal (iminophosphinoyl)(thiophosphinoyl)methanide and methanediide complexes derived from zirconium and the hafnium. Group 11 metal (iminophosphinoyl)(thiophosphinoyl)methanediide complexes have been presented as well.