dc.contributor.authorYeong, Crystal Huixian
dc.date.accessioned2014-01-28T08:47:35Z
dc.date.accessioned2017-07-23T08:44:02Z
dc.date.available2014-01-28T08:47:35Z
dc.date.available2017-07-23T08:44:02Z
dc.date.copyright2014en_US
dc.date.issued2014
dc.identifier.citationYeong, C. H. (2014). Chemistry of base-stabilized group 14 element(I) dimers. Doctoral thesis, Nanyang Technological University, Singapore.
dc.identifier.urihttp://hdl.handle.net/10356/55296
dc.description.abstractThis thesis describes the reactivity studies of an amidinate-stabilized silicon(I) dimer [LSi:-Si:L] (L = PhC(NtBu)2). The synthesis, characterization and theoretical studies of the first examples of heavier group 14 cyclobutadiene analogues which comprise of heavier group 14 elements, silicon, germanium and tin, in the four-membered skeleton are also described. Additionally, the synthesis and reactivity of an amidinate-stabilized silyliumylidene cation [LSi(DMAP)]OTf is described. Lastly, the synthesis and characterization of a germanium(I) dimer and a germylidenide anion stabilized by the 2-imino-5,6-methylenedioxylphenyl ligand is described.en_US
dc.format.extent155 p.en_US
dc.language.isoenen_US
dc.subjectDRNTU::Science::Chemistryen_US
dc.titleChemistry of base-stabilized group 14 element (I) dimersen_US
dc.typeThesis
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.contributor.supervisorSo Cheuk Wai
dc.description.degreeDOCTOR OF PHILOSOPHY (SPMS)en_US


Files in this item

FilesSizeFormatView
Yeong HuiXian Crystal_G0901721J.pdf7.643Mbapplication/pdfView/Open

This item appears in the following Collection(s)

Show simple item record