Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/55385
Title: Part 1 : Synthesis of vinyl sulfones via palladium-catalyzed sulfonylation of olefins.
Part 2 : Trienes: Synthesis via C-H Functionalization and as precursors to complex molecules.
Authors: Wang, Wee Jian.
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Issue Date: 2013
Abstract: In Part 1, we would like to introduce a new protocol for the synthesis of vinyl sulfones via palladium-catalyzed sulfonylation of olefins using Pd(PhCN)2Cl2 (10 mol%) as a catalyst and K2CO3 (0.5 equiv) in dioxane. Both vinyl-pyridine and enamides were able to afford the corresponding products in moderate to good yields using this novel method. Substituents are well tolerated in this reaction furnishing products which are potential useful intermediate that can be used for further transformation. Next in Part 2, we would like to present results from explorative studies on the synthesis of triene via C‒H functionalization and the transformation of trienes to complex molecules.
URI: http://hdl.handle.net/10356/55385
Fulltext Permission: restricted
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

Files in This Item:
File Description SizeFormat 
Wang Wee Jian.pdf
  Restricted Access
2.36 MBAdobe PDFView/Open

Google ScholarTM

Check

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.