Please use this identifier to cite or link to this item:
Title: Synthesis of base-stabilized heavier low valent group 14 complexes
Authors: Chia, Siew Peng
Keywords: DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis
Issue Date: 2014
Source: Chia, S. P. (2014). Synthesis of base-stabilized heavier low valent group 14 complexes. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: The synthesis and the structures of group 14 element(I) dimers [LEEL] [L = 2,6-(CH=NR)2C6H3, E = Ge, Sn, Pb] and their reduction to afford the respective group 14 element anions are discussed. The treatment of [LGeGeL] and [LSnSnL] with excess KC8, afforded the germylidenide anion [LGeK.TMEDA] and stannylidenide anion [LSnK.THF] respectively. The first base-stabilized lead(I) dimer [LPb-PbL] was synthesized by oxidation of plumbylidenide anion [LPbLi.(THF)4] with SnCl2. Reversely, the reduction of [LPb-PbL] with lithium afforded the aromatic plumbylidenide anion .
DOI: 10.32657/10356/55388
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

Files in This Item:
File Description SizeFormat 
Thesis_Chia Siew Peng.pdf2.28 MBAdobe PDFThumbnail

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.