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Title: Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
Authors: Gan, Kennard Jun Hao
Keywords: DRNTU::Science::Chemistry::Inorganic chemistry::Metals
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Issue Date: 2016
Source: Gan, K. J. H. (2016). Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis comprises the successful application of cyclometalated Palladium(II)-complexes as catalysts toward aryl boronic acid addition onto a variety of unsaturated enones.
DOI: 10.32657/10356/65930
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

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