Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/79334
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dc.contributor.authorLi, Ying-Zhouen
dc.contributor.authorLeong, Weng Keeen
dc.date.accessioned2015-09-04T04:10:29Zen
dc.date.accessioned2019-12-06T13:22:48Z-
dc.date.available2015-09-04T04:10:29Zen
dc.date.available2019-12-06T13:22:48Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationLi, Y.-Z., & Leong, W. K. (2015). Raft-like osmium- and ruthenium-antimony carbonyl clusters. Journal of Organometallic Chemistry, 812, 217-225.en
dc.identifier.issn0022-328Xen
dc.identifier.urihttps://hdl.handle.net/10356/79334-
dc.description.abstractThe higher nuclearity raft-like cluster Os6(CO)20(μ-SbPh2)2, 5-Os, was isolated from the base hydrolysis of Os3(CO)11(SbPh2Cl), 1-Os. The ruthenium analogue, viz., Ru6(CO)20(μ-SbPh2)2, 5-Ru, was obtained from the reduction of Ru3(CO)12, 7-Ru, with the benzophenone ketyl radical followed by treatment with SbPh2Cl. These clusters undergo facile ligand substitution reactions with two-electron donors to afford the mono- and disubstituted derivatives M6(CO)20-n(μ-SbPh2)2(L)n, (M = Ru or Os; n = 1 (8) or 2 (9); L = PMe3 (a), PPh3 (b), or tBuNC (c)).en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent9p.en
dc.language.isoenen
dc.relation.ispartofseriesJournal of organometallic chemistryen
dc.rights© 2015 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1016/j.jorganchem.2015.06.007].en
dc.subjectDRNTU::Science::Chemistry::Organic chemistry::Organometallic compoundsen
dc.titleRaft-like osmium- and ruthenium-antimony carbonyl clustersen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1016/j.jorganchem.2015.06.007en
dc.description.versionAccepted versionen
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