Please use this identifier to cite or link to this item:
Title: Raft-like osmium- and ruthenium-antimony carbonyl clusters
Authors: Li, Ying-Zhou
Leong, Weng Kee
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2015
Source: Li, Y.-Z., & Leong, W. K. (2015). Raft-like osmium- and ruthenium-antimony carbonyl clusters. Journal of Organometallic Chemistry, 812, 217-225.
Series/Report no.: Journal of organometallic chemistry
Abstract: The higher nuclearity raft-like cluster Os6(CO)20(μ-SbPh2)2, 5-Os, was isolated from the base hydrolysis of Os3(CO)11(SbPh2Cl), 1-Os. The ruthenium analogue, viz., Ru6(CO)20(μ-SbPh2)2, 5-Ru, was obtained from the reduction of Ru3(CO)12, 7-Ru, with the benzophenone ketyl radical followed by treatment with SbPh2Cl. These clusters undergo facile ligand substitution reactions with two-electron donors to afford the mono- and disubstituted derivatives M6(CO)20-n(μ-SbPh2)2(L)n, (M = Ru or Os; n = 1 (8) or 2 (9); L = PMe3 (a), PPh3 (b), or tBuNC (c)).
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2015.06.007
Schools: School of Physical and Mathematical Sciences 
Rights: © 2015 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

Files in This Item:
File Description SizeFormat 
Raft-like Osmium- and Ruthenium-Antimony Carbonyl Clusters.pdfMain article505.94 kBAdobe PDFThumbnail

Citations 20

Updated on Jul 17, 2024

Web of ScienceTM
Citations 20

Updated on Oct 30, 2023

Page view(s) 50

Updated on Jul 20, 2024

Download(s) 20

Updated on Jul 20, 2024

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.