Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/79348
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dc.contributor.authorYang, Junfengen
dc.contributor.authorSeto, Yuan Wahen
dc.contributor.authorYoshikai, Naohikoen
dc.date.accessioned2015-08-21T08:30:45Zen
dc.date.accessioned2019-12-06T13:23:07Z-
dc.date.available2015-08-21T08:30:45Zen
dc.date.available2019-12-06T13:23:07Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationYang, J., Seto, Y. W., & Yoshikai, N. (2015). Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation. ACS Catalysis, 5(5), 3054-3057.en
dc.identifier.urihttps://hdl.handle.net/10356/79348-
dc.description.abstractA low-valent cobalt catalyst generated from cobalt(II) bromide, a diphosphine ligand, and zinc powder promotes intermolecular hydroacylation of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents, which affords, upon acidic hydrolysis, ketone products in moderate to good yields with high linear selectivity. The reaction is applicable to styrenes, vinylsilanes, and aliphatic olefins as well as to various aryl and heteroaryl aldimines. The cobalt catalysis features a distinctively lower reaction temperature (60 °C) compared with those required for the same type of transformations catalyzed by rhodium complexes (typically 130–150 °C).en
dc.format.extent4 p.en
dc.language.isoenen
dc.relation.ispartofseriesACS catalysisen
dc.rights© 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by ACS Catalysis, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acscatal.5b00581].en
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleCobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/acscatal.5b00581en
dc.description.versionAccepted versionen
item.grantfulltextopen-
item.fulltextWith Fulltext-
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