Please use this identifier to cite or link to this item:
Full metadata record
DC FieldValueLanguage
dc.contributor.authorYang, Junfengen
dc.contributor.authorSeto, Yuan Wahen
dc.contributor.authorYoshikai, Naohikoen
dc.identifier.citationYang, J., Seto, Y. W., & Yoshikai, N. (2015). Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation. ACS Catalysis, 5(5), 3054-3057.en
dc.description.abstractA low-valent cobalt catalyst generated from cobalt(II) bromide, a diphosphine ligand, and zinc powder promotes intermolecular hydroacylation of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents, which affords, upon acidic hydrolysis, ketone products in moderate to good yields with high linear selectivity. The reaction is applicable to styrenes, vinylsilanes, and aliphatic olefins as well as to various aryl and heteroaryl aldimines. The cobalt catalysis features a distinctively lower reaction temperature (60 °C) compared with those required for the same type of transformations catalyzed by rhodium complexes (typically 130–150 °C).en
dc.format.extent4 p.en
dc.relation.ispartofseriesACS catalysisen
dc.rights© 2015 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by ACS Catalysis, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].en
dc.subjectDRNTU::Science::Chemistry::Organic chemistryen
dc.titleCobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.description.versionAccepted versionen
item.fulltextWith Fulltext-
Appears in Collections:SPMS Journal Articles

Citations 5

Updated on Jul 19, 2024

Web of ScienceTM
Citations 5

Updated on Oct 28, 2023

Page view(s) 20

Updated on Jul 20, 2024

Download(s) 20

Updated on Jul 20, 2024

Google ScholarTM




Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.