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Title: The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne : formation of a η3-tetraenyl transition metal complex
Authors: Mak, Garvin Kar Hang
Fan, Wai Yip
Sridevi, Venugopal Shanmugham
Leong, Weng Kee
Keywords: Chemistry and Biological Chemistry
Issue Date: 2013
Source: Mak, K. H. G., Fan, W. Y., Sridevi, V. S., & Leong, W. K. (2013). The reaction of [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne: Formation of a η3-tetraenyl transition metal complex. Journal of Organometallic Chemistry, 739, 52-56.
Series/Report no.: Journal of Organometallic Chemistry
Abstract: Reaction of the dimeric species [Cp*IrCl2]2 with 2-methyl-1-butene-3-yne results in C–C bond formation between two alkyne molecules and their coordination to an iridium center to form a complex containing a η3-tetraenyl ligand. The reaction pathway has been studied experimentally and computationally.
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2013.04.037
Schools: School of Physical and Mathematical Sciences 
Rights: © 2013 Elsevier B.V. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of Organometallic Chemistry, Elsevier B.V. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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