Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/80263
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dc.contributor.authorLei, Chuanhuen
dc.contributor.authorJin, Xiaojiaen
dc.contributor.authorZhou, Jianrong (Steve)en
dc.date.accessioned2016-05-10T07:25:46Zen
dc.date.accessioned2019-12-06T13:46:06Z-
dc.date.available2016-05-10T07:25:46Zen
dc.date.available2019-12-06T13:46:06Z-
dc.date.copyright2015en
dc.date.issued2015en
dc.identifier.citationLei, C., Jin, X., & Zhou, J. (2015). Palladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodides. Angewandte Chemie International Edition, 54(45), 13397-13400.en
dc.identifier.issn1433-7851en
dc.identifier.urihttps://hdl.handle.net/10356/80263-
dc.description.abstractThree-component couplings were achieved from common aryl halides, alkyl halides, and heteroarenes under palladium and norbornene co-catalysis. The reaction forges hindered aryl–heteroaryl bonds and introduces ortho-alkyl groups to aryl rings. Various heterocycles such as oxazoles, thiazoles and thiophenes underwent efficient coupling. The heteroarenes were deprotonated in situ by bases without the assistance of palladium catalysts.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent4 p.en
dc.language.isoenen
dc.relation.ispartofseriesAngewandte Chemie International Editionen
dc.rights© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en
dc.subjectcross-couplingen
dc.subjectheterocyclesen
dc.subjectpalladiumen
dc.subjectC-H activationen
dc.subjectsynthetic methoden
dc.titlePalladium-Catalyzed Heteroarylation and Concomitant ortho-Alkylation of Aryl Iodidesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1002/anie.201507128en
dc.identifier.rims191130en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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