Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/80269
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dc.contributor.authorLei, Chuanhuen
dc.contributor.authorJin, Xiaojiaen
dc.contributor.authorZhou, Jianrong (Steve)en
dc.date.accessioned2016-05-10T07:04:31Zen
dc.date.accessioned2019-12-06T13:46:13Z-
dc.date.available2016-05-10T07:04:31Zen
dc.date.available2019-12-06T13:46:13Z-
dc.date.copyright2016en
dc.date.issued2016en
dc.identifier.citationLei, C., Jin, X., & Zhou, J. (2016). Palladium-Catalyzed Alkynylation and Concomitant ortho Alkylation of Aryl Iodides. ACS Catalysis, 6(3), 1635-1639.en
dc.identifier.issn2155-5435en
dc.identifier.urihttps://hdl.handle.net/10356/80269-
dc.description.abstractWe report an efficient alkynylation reaction of aryl iodides with simultaneous ortho-alkylaton of aryl rings. The reaction between three simple reagents—aryl halides, alkynes, and alkyl halides—formed aryl–alkynyl bonds carrying hindered aryl rings in one step. The reaction proceeded via a Catellani-type pathway in the presence of norbornene. From a synthetic perspective, this reaction allows quick access toward many 1,2,3-substituted arenes and multiply substituted benzofurans, after manipulation of alkyne groups. These compounds are difficult to synthesize otherwise.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent5 p.en
dc.language.isoenen
dc.relation.ispartofseriesACS Catalysisen
dc.rights© 2016 American Chemical Society.en
dc.subjectalkynylationen
dc.subjectCH activationen
dc.subjectCatellani reactionen
dc.subjectbenzofuranen
dc.subjectpalladium catalysisen
dc.titlePalladium-Catalyzed Alkynylation and Concomitant ortho Alkylation of Aryl Iodidesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/acscatal.6b00169en
dc.identifier.rims191132en
item.fulltextNo Fulltext-
item.grantfulltextnone-
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