Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/80539
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dc.contributor.authorAbdul Sadeeren
dc.contributor.authorPullarkat, Sumod Appukuttanen
dc.contributor.authorShand, Sam S.en
dc.contributor.authorLi, Yongxinen
dc.contributor.authorVu, Minh Duyen
dc.contributor.authorFoo, Ce Qingen
dc.date.accessioned2019-11-07T06:31:26Zen
dc.date.accessioned2019-12-06T13:51:46Z-
dc.date.available2019-11-07T06:31:26Zen
dc.date.available2019-12-06T13:51:46Z-
dc.date.issued2018en
dc.identifier.citationVu, M. D., Foo, C. Q., Abdul Sadeer., Shand, S. S., Li, Y., & Pullarkat, S. A. (2018). Triflic-acid-catalyzed tandem allylic substitution–cyclization reaction of alcohols with thiophenols—facile access to polysubstituted thiochromans. ACS Omega, 3(8), 8945-8951. doi:10.1021/acsomega.8b01305en
dc.identifier.urihttps://hdl.handle.net/10356/80539-
dc.description.abstractHitherto inaccessible multisubstituted thiochroman derivatives were constructed via the one-pot reaction of thiophenols with allylic alcohols catalyzed by 0.2 equiv triflic acid under metal-free conditions. A variety of thiochroman derivatives can be obtained by this straightforward protocol that allows the introduction of up to four substituents at various locations on the thiochroman skeleton. Relative conformations of all isolated products were confirmed by NOESY NMR studies, and a stepwise mechanism, proceeding via an allylic substitution-intramolecular cyclization protocol, is proposed on the basis of NMR experiments.en
dc.format.extent7 p.en
dc.language.isoenen
dc.relation.ispartofseriesACS Omegaen
dc.rights© 2018 American Chemical Society. This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.en
dc.subjectScience::Chemistry::Biochemistryen
dc.subjectThiophenolsen
dc.subjectThiochromansen
dc.titleTriflic-acid-catalyzed tandem allylic substitution–cyclization reaction of alcohols with thiophenols—facile access to polysubstituted thiochromansen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1021/acsomega.8b01305en
dc.description.versionPublished versionen
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