Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/81017
Title: Comprehensive Study on Chain-End Transformation of Polymer–Iodides with Amines for Synthesizing Various Chain-End Functionalized Polymers
Authors: Chen, Chen
Xiao, Longqiang
Goto, Atsushi
Keywords: Chain-end Functionalized Polymers
Organocatalyzed Living Radical Polymerization
Issue Date: 2016
Source: Chen, C., Xiao, L., & Goto, A. (2016). Comprehensive Study on Chain-End Transformation of Polymer–Iodides with Amines for Synthesizing Various Chain-End Functionalized Polymers. Macromolecules, 49(24), 9425-9440.
Series/Report no.: Macromolecules
Abstract: Chain-end functionalized polymers (polymer–NHR) were successfully synthesized through the reaction of a polymer–iodide (polymer–I) with a primary amine (NH2R), where the R moiety contains a functional group. This reaction was comprehensively studied for three different polymers, i.e., poly(butyl acrylate), polystyrene, and poly(methyl methacrylate), and six different functional amines with phenyl, alkyl, triethoxysilyl, SH, OH, and NH2 functionalities, and the detailed reaction mechanisms were probed by using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI–TOF–MS). This chain-end transformation reaction is easy to perform, amenable to various polymers and functional amines, and also quantitative and selective in many cases. This synthetic technique may serve as a useful platform method for synthesizing various chain-end functionalized polymers.
URI: https://hdl.handle.net/10356/81017
http://hdl.handle.net/10220/43450
ISSN: 0024-9297
DOI: 10.1021/acs.macromol.6b02291
Schools: School of Physical and Mathematical Sciences 
Rights: © 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Macromolecules, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/acs.macromol.6b02291].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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