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dc.contributor.authorPramana, Stevin S.en
dc.contributor.authorCavallaro, Andreaen
dc.contributor.authorLi, Chengen
dc.contributor.authorHandoko, Albertus D.en
dc.contributor.authorChan, Kuang Wenen
dc.contributor.authorWalker, Robert J.en
dc.contributor.authorRegoutz, Annaen
dc.contributor.authorHerrin, Jason Scotten
dc.contributor.authorYeo, Boon Siangen
dc.contributor.authorPayne, David J.en
dc.contributor.authorKilner, John A.en
dc.contributor.authorRyan, Mary P.en
dc.contributor.authorSkinner, Stephen J.en
dc.identifier.citationPramana, S. S., Cavallaro, A., Li, C., Handoko, A. D., Chan, K. W., Walker, R. J., … Skinner, S. J. (2018). Crystal structure and surface characteristics of Sr-doped GdBaCo2O6−δ double perovskites : oxygen evolution reaction and conductivity. Journal of Materials Chemistry A, 6(13), 5335-5345. doi:10.1039/C7TA06817Den
dc.description.abstractA cheap and direct solution towards engineering better catalysts through identification of novel materials is required for a sustainable energy system. Perovskite oxides have emerged as potential candidates to replace the less economically attractive Pt and IrO2 water splitting catalysts. In this work, excellent electrical conductivity (980 S cm 1) was found for the double perovskite of composition GdBa0.6Sr0.4Co2O6 d which is consistent with a better oxygen evolution reaction activity with the onset polarisation of 1.51 V with respect to a reversible hydrogen electrode (RHE). GdBa1 xSrxCo2O6 d with increasing Sr content was found to crystallise in the higher symmetry tetragonal P4/mmm space group in comparison with the undoped GdBaCo2O6 d which is orthorhombic (Pmmm), and yields higher oxygen uptake, accompanied by higher Co oxidation states. This outstanding electrochemical performance is explained by the wider carrier bandwidth, which is a function of Co–O–Co buckling angles and Co–O bond lengths. Furthermore the higher oxygen evolution activity was observed despite the formation of non-lattice oxides (mainly hydroxide species) and enrichment of alkaline earth ions on the surface.en
dc.format.extent11 p.en
dc.relation.ispartofseriesJournal of Materials Chemistry Aen
dc.rights© 2018 The Authors (The Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectCrystal Structureen
dc.titleCrystal structure and surface characteristics of Sr-doped GdBaCo2O6−δ double perovskites : oxygen evolution reaction and conductivityen
dc.typeJournal Articleen
dc.contributor.researchEarth Observatory of Singaporeen
dc.description.versionPublished versionen
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