Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/81915
Title: A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property
Authors: Zhu, Xiao-Fei
Wang, Ning
Xie, Xiao-Yan
Hou, Rui-Bin
Zhou, De-Feng
Li, Ya-Feng
Hu, Jun
Li, Xin-Yuan
Liu, He
Nie, Wang
Keywords: Hydrothermal
Tetranuclear cluster
Luminescence
2,5-dibenzoylterephthalic acid
Crystal structure
Issue Date: 2013
Source: Zhu, X.-F., Wang, N., Xie, X.-Y., Hou, R.-B., Zhou, D.-F., Li, Y.-F., et al. (2013). A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 33(2), 277-283.
Series/Report no.: Chinese Journal of Structural Chemistry
Abstract: A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2O)2]·2H2O(1, H2L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group Pī, C33H27CdO14, Mr = 870.33, α = 12.2939(17), b = 12.5135(9), c = 13.2046(10) Å, α= 115.3190(10), β96.9140(10), γ = 109.7950(10)°, V = 1641.6(3) Å3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoKa) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I > 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with (412·63) topology, in which the tetra-nuclear [Cd4(µ3-OH)2] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail.
URI: https://hdl.handle.net/10356/81915
http://hdl.handle.net/10220/39710
ISSN: 0254-5861
Rights: © 2014 Editorial Board of Chinese Journal of Structural Chemistry. This paper was published in Chinese Journal of Structural Chemistry and is made available as an electronic reprint (preprint) with permission of Editorial Board of Chinese Journal of Structural Chemistry. The published version is available at: [http://manu30.magtech.com.cn/jghx/EN/]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:MSE Journal Articles

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