Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/81915
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dc.contributor.authorZhu, Xiao-Feien
dc.contributor.authorWang, Ningen
dc.contributor.authorXie, Xiao-Yanen
dc.contributor.authorHou, Rui-Binen
dc.contributor.authorZhou, De-Fengen
dc.contributor.authorLi, Ya-Fengen
dc.contributor.authorHu, Junen
dc.contributor.authorLi, Xin-Yuanen
dc.contributor.authorLiu, Heen
dc.contributor.authorNie, Wangen
dc.date.accessioned2016-01-19T07:05:45Zen
dc.date.accessioned2019-12-06T14:42:58Z-
dc.date.available2016-01-19T07:05:45Zen
dc.date.available2019-12-06T14:42:58Z-
dc.date.issued2013en
dc.identifier.citationZhu, X.-F., Wang, N., Xie, X.-Y., Hou, R.-B., Zhou, D.-F., Li, Y.-F., et al. (2013). A New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 33(2), 277-283.en
dc.identifier.issn0254-5861en
dc.identifier.urihttps://hdl.handle.net/10356/81915-
dc.description.abstractA unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2O)2]·2H2O(1, H2L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group Pī, C33H27CdO14, Mr = 870.33, α = 12.2939(17), b = 12.5135(9), c = 13.2046(10) Å, α= 115.3190(10), β96.9140(10), γ = 109.7950(10)°, V = 1641.6(3) Å3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoKa) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I > 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with (412·63) topology, in which the tetra-nuclear [Cd4(µ3-OH)2] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail.en
dc.format.extent7 p.en
dc.language.isoenen
dc.relation.ispartofseriesChinese Journal of Structural Chemistryen
dc.rights© 2014 Editorial Board of Chinese Journal of Structural Chemistry. This paper was published in Chinese Journal of Structural Chemistry and is made available as an electronic reprint (preprint) with permission of Editorial Board of Chinese Journal of Structural Chemistry. The published version is available at: [http://manu30.magtech.com.cn/jghx/EN/]. One print or electronic copy may be made for personal use only. Systematic or multiple reproduction, distribution to multiple locations via electronic or other means, duplication of any material in this paper for a fee or for commercial purposes, or modification of the content of the paper is prohibited and is subject to penalties under law.en
dc.subjectHydrothermalen
dc.subjectTetranuclear clusteren
dc.subjectLuminescenceen
dc.subject2,5-dibenzoylterephthalic aciden
dc.subjectCrystal structureen
dc.titleA New 3D Metal–organic Frameworks with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Propertyen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen
dc.description.versionPublished versionen
dc.identifier.urlhttp://manu30.magtech.com.cn/jghx/EN/en
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