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Title: Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration
Authors: Zhang, Zhengyang
Wells, Kym L.
Seidel, Marco T.
Tan, Howe-Siang
Keywords: Chemistry and Biological Chemistry
Issue Date: 2013
Source: Zhang, Z., Wells, K. L., Seidel, M. T., & Tan, H.-S. (2013). Fifth-Order Three-Dimensional Electronic Spectroscopy Using a Pump–Probe Configuration. The Journal of Physical Chemistry B, 117(49), 15369-15385.
Series/Report no.: The Journal of Physical Chemistry B
Abstract: We present the theoretical details and experimental demonstration of fifth-order three-dimensional (3D) electronic spectroscopy using a pump–probe beam geometry. This is achieved using a pulse shaper and appropriate phase cycling schemes. We show how 8-step and 27-step phase cycling schemes can measure purely absorptive 3D spectra as well as 3D spectra for the individual fifth-order processes that contribute to the purely absorptive spectrum. 3D spectra as a function of two separate controllable waiting time periods can be obtained. The peak shapes and positions of the peaks in the experimental measurement correspond well to theory.
ISSN: 1520-6106
DOI: 10.1021/jp4046403
Schools: School of Physical and Mathematical Sciences 
Rights: © 2013 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by The Journal of Physical Chemistry B, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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