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https://hdl.handle.net/10356/82663| Title: | Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins | Authors: | Guo, Siyu Yang, Peng Zhou, Jianrong Steve |
Keywords: | Chemistry and Biological Chemistry | Issue Date: | 2015 | Source: | Guo, S., Yang, P., & Zhou, J. S. (2015). Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins. Chemical Communications, 51(60), 12115-12117. | Series/Report no.: | Chemical Communications | Abstract: | Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates. | URI: | https://hdl.handle.net/10356/82663 http://hdl.handle.net/10220/40239 |
ISSN: | 1359-7345 | DOI: | 10.1039/C5CC01632K | Rights: | This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
| Appears in Collections: | SPMS Journal Articles |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins.pdf | 1.82 MB | Adobe PDF |  View/Open |
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