Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/82663
Title: Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins
Authors: Guo, Siyu
Yang, Peng
Zhou, Jianrong Steve
Keywords: Chemistry and Biological Chemistry
Issue Date: 2015
Source: Guo, S., Yang, P., & Zhou, J. S. (2015). Nickel-catalyzed asymmetric transfer hydrogenation of conjugated olefins. Chemical Communications, 51(60), 12115-12117.
Series/Report no.: Chemical Communications
Abstract: Asymmetric transfer hydrogenation of electron-deficient olefins is realized with nickel catalysts supported by strongly σ-donating bisphosphines. Deuterium labeling experiments point to a reaction sequence of formate decarboxylation, asymmetric hydride insertion and non-stereoselective protonation of resulting nickel enolates.
URI: https://hdl.handle.net/10356/82663
http://hdl.handle.net/10220/40239
ISSN: 1359-7345
DOI: 10.1039/C5CC01632K
Rights: This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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