Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/82664
Full metadata record
DC FieldValueLanguage
dc.contributor.authorWu, Melissa M.en
dc.contributor.authorGill, Arran M.en
dc.contributor.authorLu, Yunpengen
dc.contributor.authorLaura, Faliveneen
dc.contributor.authorLi, Yongxinen
dc.contributor.authorRakesh, Gangulyen
dc.contributor.authorLuigi, Cavalloen
dc.contributor.authorFelipe, Garcíaen
dc.date.accessioned2016-03-15T06:27:24Zen
dc.date.accessioned2019-12-06T14:59:57Z-
dc.date.available2016-03-15T06:27:24Zen
dc.date.available2019-12-06T14:59:57Z-
dc.date.issued2015en
dc.identifier.citationWu, M. M., Gill, A. M., Lu, Y., Laura, F., Li, Y., Rakesh, G., et al. (2015). Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes. Dalton Transactions, 44(34), 15166-15174.en
dc.identifier.issn1477-9226en
dc.identifier.urihttps://hdl.handle.net/10356/82664-
dc.description.abstractTreatment of a series of aromatic NHCs (IMes, SIMes, IPr and SIPr) with trimethylaluminium produced their corresponding Lewis acid–base adducts: IMes·AlMe3 (1), SIMes·AlMe3 (2), IPr·AlMe3 (3), and SIPr·AlMe3 (4). These complexes expand the few known examples of saturated NHC stabilised Group 13 complexes. Furthermore, compounds 1–4 show differential stability depending on the nature of the NHC ligand. Analyses of topographic steric maps and NHC %VBur were used to explain these differences. All the compounds have been fully characterised by multinuclear NMR spectroscopy, IR and single crystal X-ray analysis together with computational studies.en
dc.format.extent9 p.en
dc.language.isoenen
dc.relation.ispartofseriesDalton Transactionsen
dc.rightsThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectLigandsen
dc.subjectTrimethylaluminiumen
dc.titleSynthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexesen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.identifier.doi10.1039/C5DT00079Cen
dc.description.versionPublished versionen
item.grantfulltextopen-
item.fulltextWith Fulltext-
Appears in Collections:SPMS Journal Articles

SCOPUSTM   
Citations 20

18
Updated on Jul 10, 2024

Web of ScienceTM
Citations 20

15
Updated on Oct 31, 2023

Page view(s) 50

553
Updated on Jul 22, 2024

Download(s) 50

145
Updated on Jul 22, 2024

Google ScholarTM

Check

Altmetric


Plumx

Items in DR-NTU are protected by copyright, with all rights reserved, unless otherwise indicated.