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dc.contributor.authorXu, Wengangen
dc.contributor.authorPek, Jie Huien
dc.contributor.authorYoshikai, Naohikoen
dc.identifier.citationXu, W., Pek, J. H., & Yoshikai, N. (2016). Cobalt-Catalyzed, Imine-Directed Olefin Hydroarylation under Grignard-Free Conditions. Advanced Synthesis & Catalysis, 358(15), 2564-2568.en
dc.description.abstractWe report here that a cobalt catalyst generated from a cobalt(II) salt and a ligand using magnesium metal is capable of promoting hydroarylation reactions through chelation-assisted C−H activation. With the appropriate choice of the ligand and other reaction conditions, ketimine- or aldimine-directed branched selective hydroarylations of styrenes and ketimine-directed hydroarylations of vinylsilane have been achieved. The reported catalytic systems may serve as more convenient alternatives to previously developed catalytic systems employing Grignard reagents as reducing agents.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent6 p.en
dc.relation.ispartofseriesAdvanced Synthesis & Catalysisen
dc.rights© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by Advanced Synthesis & Catalysis, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].en
dc.subjectC–H activationen
dc.subjectC–C bond formationen
dc.titleCobalt-Catalyzed, Imine-Directed Olefin Hydroarylation under Grignard-Free Conditionsen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen
dc.description.versionAccepted versionen
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