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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Šolić, Ivan | en |
dc.contributor.author | Lin, Hong Xuan | en |
dc.contributor.author | Bates, Roderick Wayland | en |
dc.date.accessioned | 2019-10-03T07:56:07Z | en |
dc.date.accessioned | 2019-12-06T15:18:51Z | - |
dc.date.available | 2019-10-03T07:56:07Z | en |
dc.date.available | 2019-12-06T15:18:51Z | - |
dc.date.issued | 2018 | en |
dc.identifier.citation | Šolić, I., Lin, H. X., & Bates, R. W. (2018). Testing the veracity of claims of Lewis acid catalysis. Tetrahedron Letters, 59(50), 4434-4436. doi:10.1016/j.tetlet.2018.11.006 | en |
dc.identifier.issn | 0040-4039 | en |
dc.identifier.uri | https://hdl.handle.net/10356/83269 | - |
dc.description.abstract | Are reactions employing Lewis acids really catalysed by those Lewis acids, or by “hidden Brønsted acids”, i.e. Brønsted acids generated in situ by hydrolysis? Testing of a series of reactions using Sc(III), Fe(III), In(III) and Y(III) by addition of 2,6-di-t-butyl-4-methylpyridine reveal that all are likely to follow the latter pathway. A reaction claimed to be catalysed by CBr4 through halogen bonding is also likely to be Brønsted acid catalysed. | en |
dc.description.sponsorship | ASTAR (Agency for Sci., Tech. and Research, S’pore) | en |
dc.format.extent | 3 p. | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Tetrahedron Letters | en |
dc.rights | © 2018 Elsevier. All rights reserved. This paper was published in Tetrahedron Letters and is made available with permission of Elsevier. | en |
dc.subject | Brønsted | en |
dc.subject | Lewis | en |
dc.subject | Science::Chemistry::Organic chemistry | en |
dc.title | Testing the veracity of claims of Lewis acid catalysis | en |
dc.type | Journal Article | en |
dc.contributor.school | School of Physical and Mathematical Sciences | en |
dc.identifier.doi | 10.1016/j.tetlet.2018.11.006 | en |
dc.description.version | Accepted version | en |
item.fulltext | With Fulltext | - |
item.grantfulltext | open | - |
Appears in Collections: | SPMS Journal Articles |
Files in This Item:
File | Description | Size | Format | |
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Veracity TL NTUDR.pdf | accepted manuscript | 218.72 kB | Adobe PDF | View/Open |
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