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dc.contributor.authorCao, Feifeien
dc.contributor.authorZhao, Meitingen
dc.contributor.authorYu, Yifuen
dc.contributor.authorChen, Boen
dc.contributor.authorHuang, Yingen
dc.contributor.authorYang, Jianen
dc.contributor.authorCao, Xiehongen
dc.contributor.authorLu, Qipengen
dc.contributor.authorZhang, Xiaoen
dc.contributor.authorZhang, Zhichengen
dc.contributor.authorTan, Chaoliangen
dc.contributor.authorZhang, Huaen
dc.identifier.citationCao, F., Zhao, M., Yu, Y., Chen, B., Huang, Y., Yang, J., et al. (2016). Synthesis of Two-Dimensional CoS1.097/Nitrogen-Doped Carbon Nanocomposites Using Metal–Organic Framework Nanosheets as Precursors for Supercapacitor Application. Journal of the American Chemical Society, 138(22), 6924-6927.en
dc.description.abstractTwo-dimensional (2D) metal–organic framework (MOF) nanosheets are attracting increasing research interest. Here, for the first time, we report the facile synthesis of 2D porphyrin paddlewheel framework-3 (PPF-3) MOF nanosheets with thickness of ca. 12–43 nm. Through the simultaneous sulfidation and carbonization of PPF-3 MOF nanosheets, we have prepared the 2D nanocomposite of CoS1.097 nanoparticles (NPs) and nitrogen-doped carbon, referred to as CoSNC, in which the CoS1.097 NPs with size of ca. 10 nm are embedded in the nitrogen-doped carbon matrix. As a proof-of-concept application, the obtained 2D CoSNC nanocomposite is used as an electrode material for a supercapacitor, which exhibits a specific capacitance of 360.1 F g–1 at a current density of 1.5 A g–1. Moreover, the composite electrode also shows high rate capability. Its specific capacitance delivered at a current density of 30.0 A g–1 retains 56.8% of the value at 1.5 A g–1.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent5 p.en
dc.relation.ispartofseriesJournal of the American Chemical Societyen
dc.rights© 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].en
dc.subjectMetal-organic frameworken
dc.titleSynthesis of Two-Dimensional CoS1.097/Nitrogen-Doped Carbon Nanocomposites Using Metal–Organic Framework Nanosheets as Precursors for Supercapacitor Applicationen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Materials Science & Engineeringen
dc.contributor.researchCentre for Programmable Materialsen
dc.description.versionAccepted versionen
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