Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/83381
Title: Part I α,β-dehydrogenation of carbonyl compounds via selenium reagents elimination Part II Indium catalyzed cyclization reaction of acrylate
Authors: Zhang, Qiuchi
Keywords: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
DRNTU::Science::Chemistry::Organic chemistry::Organic spectroscopy
DRNTU::Science::Chemistry::Organic chemistry::Oxidation
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Issue Date: 2019
Source: Zhang, Q. (2019). Part I α,β-dehydrogenation of carbonyl compounds via selenium reagents elimination Part II Indium catalyzed cyclization reaction of acrylate. Doctoral thesis, Nanyang Technological University, Singapore.
Abstract: In in first part, selenium conducted elimination reaction of thioesters was discussed. This is a two-step one-pot reaction, which firstly give an alpha selenium substitute of thioesters, then oxidize the selenium intermediate gives an elimination reaction, which lead to the α,β-unsaturated thioester as the product. In in second part, an In(III)-TMSBr-catalyzed aryldihydronaphthalene derivatives synthesis method is discussed, the indium catalyst makes the aryl alkyne react with two molecules of acrylate and gives an aryldihydronaphthalene derivative as the product.
URI: https://hdl.handle.net/10356/83381
http://hdl.handle.net/10220/47601
DOI: 10.32657/10220/47601
Schools: School of Physical and Mathematical Sciences 
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Theses

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