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dc.contributor.authorThia, Larissaen
dc.contributor.authorXie, Mingshien
dc.contributor.authorLiu, Zhaolinen
dc.contributor.authorGe, Xiaomingen
dc.contributor.authorLu, Yizhongen
dc.contributor.authorFong, Wenmei Eileenen
dc.contributor.authorWang, Xinen
dc.identifier.citationThia, L., Xie, M., Liu, Z., Ge, X., Lu, Y., Fong, W. E., et al. (2016). Copper-Modified Gold Nanoparticles as Highly Selective Catalysts for Glycerol Electro-Oxidation in Alkaline Solution. ChemCatChem, 8(20), 3272-3278.en
dc.description.abstractThe C3 selectivity of carbon-supported Au nanoparticles for glycerol electro-oxidation was significantly enhanced by the interaction of Au with electro-deposited Cu species. Notably, the C3 selectivity of supported Au nanoparticles doubled after 90 min of Cu electro-deposition at +0.015 V. This result was obtained if glycerol electro-oxidation was performed at +0.1 V for 2 h. The most selective catalysts contained an Au+ species that was generated by an interaction between Au and electro-deposited Cu2O. The presence of Au+ increased the selectivity to glycerate and tartronate and suppressed C−C bond cleavage to glycolate and formate simultaneously.en
dc.description.sponsorshipMOE (Min. of Education, S’pore)en
dc.format.extent25 p.en
dc.rights© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the author created version of a work that has been peer reviewed and accepted for publication by ChemCatChem, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [].en
dc.titleCopper-Modified Gold Nanoparticles as Highly Selective Catalysts for Glycerol Electro-Oxidation in Alkaline Solutionen
dc.typeJournal Articleen
dc.contributor.schoolSchool of Chemical and Biomedical Engineeringen
dc.contributor.schoolSchool of Materials Science & Engineeringen
dc.contributor.researchNanyang Environment and Water Research Instituteen
dc.description.versionAccepted versionen
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