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https://hdl.handle.net/10356/84965
Title: | Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles | Authors: | Jiao, Zhiwei Chee, Kwok Wei Zhou, Jianrong Steve |
Keywords: | Palladium catalysis Alkylnitrile |
Issue Date: | 2016 | Source: | Jiao, Z., Chee, K. W., & Zhou, J. S. (2016). Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles. Journal of the American Chemical Society, 138(50), 16240-16243. | Series/Report no.: | Journal of the American Chemical Society | Abstract: | Asymmetric arylation of alkylnitriles forms quaternary stereocenters in good enantiocontrol for the first time. A lithium heterodimer consisting of an alkylnitrile anion and a disilylamide ion is the actual species responsible for the stereodetermining transmetalation in the catalytic cycle. | URI: | https://hdl.handle.net/10356/84965 http://hdl.handle.net/10220/43605 |
ISSN: | 0002-7863 | DOI: | 10.1021/jacs.6b11610 | Schools: | School of Physical and Mathematical Sciences | Rights: | © 2016 American Chemical Society. This is the author created version of a work that has been peer reviewed and accepted for publication by Journal of the American Chemical Society, American Chemical Society. It incorporates referee’s comments but changes resulting from the publishing process, such as copyediting, structural formatting, may not be reflected in this document. The published version is available at: [http://dx.doi.org/10.1021/jacs.6b11610]. | Fulltext Permission: | open | Fulltext Availability: | With Fulltext |
Appears in Collections: | SPMS Journal Articles |
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Palladium-Catalyzed Asymmetric α-Arylation of Alkylnitriles.pdf | 720.12 kB | Adobe PDF | View/Open |
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