Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/85595
Title: Carbene-catalyzed reductive coupling of nitrobenzyl bromide and nitroalkene via the single-electron-transfer (SET) process and formal 1,4-addition
Authors: Wang, Yuhuang
Du, Yu
Huang, Xuan
Wu, Xingxing
Zhang, Yuexia
Yang, Song
Chi, Robin Yonggui
Keywords: Science::Chemistry
Issue Date: 2017
Source: Wang, Y., Du, Y., Huang, X., Wu, X., Zhang, Y., Yang, S. & Chi, R. Y. (2017). Carbene-catalyzed reductive coupling of nitrobenzyl bromide and nitroalkene via the single-electron-transfer (SET) process and formal 1,4-addition. Organic Letters, 19(3), 632-635. https://dx.doi.org/10.1021/acs.orglett.6b03792
Project: NRF-NRFI2016-06
MOE2013-T2-2-003
Journal: Organic Letters
Abstract: A carbene-catalyzed reductive 1,4-addition of nitrobenzyl bromides to nitroalkenes is disclosed. The reaction proceeds via a carbene-enabled single-electron-transfer process that generates radicals as key intermediates. The present study expands the potentials of carbene catalysis and offers unusual transformations for common substrates in organic synthesis.
URI: https://hdl.handle.net/10356/85595
http://hdl.handle.net/10220/43776
ISSN: 1523-7060
DOI: 10.1021/acs.orglett.6b03792
Rights: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.6b03792.
Fulltext Permission: open
Fulltext Availability: With Fulltext
Appears in Collections:SPMS Journal Articles

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