Please use this identifier to cite or link to this item: https://hdl.handle.net/10356/85595
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dc.contributor.authorWang, Yuhuangen_US
dc.contributor.authorDu, Yuen_US
dc.contributor.authorHuang, Xuanen_US
dc.contributor.authorWu, Xingxingen_US
dc.contributor.authorZhang, Yuexiaen_US
dc.contributor.authorYang, Songen_US
dc.contributor.authorChi, Robin Yongguien_US
dc.date.accessioned2017-09-20T09:06:20Zen
dc.date.accessioned2019-12-06T16:06:48Z-
dc.date.available2017-09-20T09:06:20Zen
dc.date.available2019-12-06T16:06:48Z-
dc.date.issued2017-
dc.identifier.citationWang, Y., Du, Y., Huang, X., Wu, X., Zhang, Y., Yang, S. & Chi, R. Y. (2017). Carbene-catalyzed reductive coupling of nitrobenzyl bromide and nitroalkene via the single-electron-transfer (SET) process and formal 1,4-addition. Organic Letters, 19(3), 632-635. https://dx.doi.org/10.1021/acs.orglett.6b03792en_US
dc.identifier.issn1523-7060en_US
dc.identifier.urihttps://hdl.handle.net/10356/85595-
dc.description.abstractA carbene-catalyzed reductive 1,4-addition of nitrobenzyl bromides to nitroalkenes is disclosed. The reaction proceeds via a carbene-enabled single-electron-transfer process that generates radicals as key intermediates. The present study expands the potentials of carbene catalysis and offers unusual transformations for common substrates in organic synthesis.en_US
dc.description.sponsorshipMinistry of Education (MOE)en_US
dc.description.sponsorshipNanyang Technological Universityen_US
dc.description.sponsorshipNational Research Foundation (NRF)en_US
dc.language.isoenen_US
dc.relationNRF-NRFI2016-06en_US
dc.relationMOE2013-T2-2-003en_US
dc.relation.ispartofOrganic Lettersen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.6b03792.en_US
dc.subjectScience::Chemistryen_US
dc.titleCarbene-catalyzed reductive coupling of nitrobenzyl bromide and nitroalkene via the single-electron-transfer (SET) process and formal 1,4-additionen_US
dc.typeJournal Articleen
dc.contributor.schoolSchool of Physical and Mathematical Sciencesen_US
dc.identifier.doi10.1021/acs.orglett.6b03792-
dc.description.versionAccepted versionen_US
dc.identifier.issue3en_US
dc.identifier.volume19en_US
dc.identifier.spage632en_US
dc.identifier.epage635en_US
dc.subject.keywordsSingle-Electron-Transferen_US
dc.subject.keywordsNitrobenzyl Bromideen_US
dc.description.acknowledgementWe acknowledge financial support by the Singapore National Research Foundation (NRF-NRFI2016-06), the Ministry of Education of Singapore (MOE2013-T2-2-003), Nanyang Technological University (NTU, Singapore), China’s Ministry of Education, National Key program for Basic Research (No. 2010CB 126105), Thousand Talent Plan (700059143302), and National Natural Science Foundation of China (No. 21132003; No. 21472028) and support by the Guizhou Province Returned Oversea Student Science and Technology Activity Program, Science and Technology of Guizhou Province, and Guizhou University.en_US
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